TY - JOUR
T1 - On the shape of the cyclic voltammetry peaks of species irreversibly adsorbed on electrode surfaces
AU - Gerischer, H.
AU - Scherson, Daniel Alberto
PY - 1985/7/10
Y1 - 1985/7/10
N2 - A theory has been developed which accounts for certain deviations from the ideal cyclic voltammetric behavior of molecules adsorbed irreversibly on electrode surfaces. This new model considers explicitly the interactions of the electric field at the interface with the permanent dipole moment of the adsorbed species. Good quantitative agreement has been obtained with experimental data reported earlier in the literature.
AB - A theory has been developed which accounts for certain deviations from the ideal cyclic voltammetric behavior of molecules adsorbed irreversibly on electrode surfaces. This new model considers explicitly the interactions of the electric field at the interface with the permanent dipole moment of the adsorbed species. Good quantitative agreement has been obtained with experimental data reported earlier in the literature.
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U2 - 10.1016/0368-1874(85)85624-0
DO - 10.1016/0368-1874(85)85624-0
M3 - Article
AN - SCOPUS:46549093381
SN - 0022-0728
VL - 189
SP - 35
EP - 38
JO - Journal of Electroanalytical Chemistry
JF - Journal of Electroanalytical Chemistry
IS - 1
ER -