One pot direct catalytic conversion of cellulose to C3 and C4 hydrocarbons using Pt/H-USY zeolite catalyst at low temperature

Shuhei Ogo*, Taku Nishio, Hikaru Sekine, Ayumu Onda, Yasushi Sekine

*この研究の対応する著者

研究成果: Article査読

11 被引用数 (Scopus)

抄録

One-pot direct catalytic conversion of cellulose to light hydrocarbon at low temperature (443 K) in the presence of Pt-zeolite catalysts and water was investigated. Results revealed that Pt supported on H+-form ultra stable Y-type (H-USY) zeolite catalyst (Pt/H-USY) enabled direct conversion of cellulose into C3 and C4 hydrocarbons without hydrogen and other expensive reagents. This production trend is attributable to the bifunctional catalysis of supported Pt and acid site in H-USY zeolite, which has a large pore system and effective acidity. Results revealed that the pre-treatment of catalyst was important for selective olefin production. Air-oxidized Pt/H-USY catalyst showed higher olefin selectivity than the catalyst reduced with hydrogen. The Pt/H-USY catalysts showed high stability under the reaction condition. Results suggest that C5 sugars were the reaction intermediate for the C3 hydrocarbons, and C6 sugars were the intermediate for C4 hydrocarbon formation from cellulose over Pt/H-USY catalysts.

本文言語English
ページ(範囲)123-129
ページ数7
ジャーナルFuel Processing Technology
141
DOI
出版ステータスPublished - 2016 1月 1

ASJC Scopus subject areas

  • 化学工学(全般)
  • 燃料技術
  • エネルギー工学および電力技術

フィンガープリント

「One pot direct catalytic conversion of cellulose to C3 and C4 hydrocarbons using Pt/H-USY zeolite catalyst at low temperature」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

引用スタイル