One-step synthesis of nanoporous titanosiloxane-based materials with isolated Ti sites using cage siloxane as a building block

Takuya Hikino, Koki Fujino, Naoto Sato, Hiroaki Wada, Kazuyuki Kuroda, Atsushi Shimojima*

*この研究の対応する著者

研究成果: Article査読

抄録

Siloxane-based nanoporous materials have a wide range of applications. In this study, a double-four-ring cage siloxane modified with dimethylsilanol groups at eight vertices was cross-linked via reaction with titanium(IV) tetraethoxide to construct a three-dimensional network with SiOTi bonds, producing a nanoporous material. The product exhibited catalytic activity for the liquid-phase oxidation of cyclohexene with relatively high selectivity. This building block approach opens a new route to nanoporous materials composed of fully inorganic SiOSi and SiOTi linkages.

本文言語English
ページ(範囲)1643-1647
ページ数5
ジャーナルChemistry Letters
50
9
DOI
出版ステータスPublished - 2021 9

ASJC Scopus subject areas

  • 化学 (全般)

フィンガープリント

「One-step synthesis of nanoporous titanosiloxane-based materials with isolated Ti sites using cage siloxane as a building block」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

引用スタイル