Organocatalyst-mediated enantioselective intramolecular aldol reaction featuring the rare combination of aldehyde as nucleophile and ketone as electrophile

Yujiro Hayashi, Hiromi Sekizawa, Junichiro Yamaguchi, Hiroaki Gotoh

研究成果: Article

46 引用 (Scopus)

抜粋

(Chemical Equation Presented) The trifluoroacetic acid salt of 2-(pyrrolidinylmethyl)pyrrolidine was found to be an effective organocatalyst of an asymmetric intramolecular aldol reaction, affording bicyclo[4.3.0]nonane derivatives with a high enantioselectivity, in which the rare combination of aldehyde as a nucleophile and ketone as an electrophile was realized.

元の言語English
ページ(範囲)6493-6499
ページ数7
ジャーナルJournal of Organic Chemistry
72
発行部数17
DOI
出版物ステータスPublished - 2007 8 17
外部発表Yes

ASJC Scopus subject areas

  • Organic Chemistry

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