Organocatalyst-mediated enantioselective intramolecular aldol reaction featuring the rare combination of aldehyde as nucleophile and ketone as electrophile

Yujiro Hayashi*, Hiromi Sekizawa, Junichiro Yamaguchi, Hiroaki Gotoh

*この研究の対応する著者

研究成果: Article査読

50 被引用数 (Scopus)

抄録

(Chemical Equation Presented) The trifluoroacetic acid salt of 2-(pyrrolidinylmethyl)pyrrolidine was found to be an effective organocatalyst of an asymmetric intramolecular aldol reaction, affording bicyclo[4.3.0]nonane derivatives with a high enantioselectivity, in which the rare combination of aldehyde as a nucleophile and ketone as an electrophile was realized.

本文言語English
ページ(範囲)6493-6499
ページ数7
ジャーナルJournal of Organic Chemistry
72
17
DOI
出版ステータスPublished - 2007 8月 17
外部発表はい

ASJC Scopus subject areas

  • 有機化学

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