Osmium organosol on DNA: Application in catalytic hydrogenation reaction and in SERS studies

S. Anantharaj, U. Nithiyanantham, Sivasankara Rao Ede, Subrata Kundu*

*この研究の対応する著者

研究成果: Article査読

35 被引用数 (Scopus)

抄録

Osmium (Os) organosol on DNA scaffold has been synthesized by utilizing a homogeneous reduction route. The synthesis was done by the reduction of OsO4 with tetrabutylammonium borohydride (TBABH4) in the presence of DNA in acetone within 10 min of stirring at room temperature. Different morphologies were synthesized by varying the DNA to OsO4 molar ratio and controlling the other reaction parameters. The eventual diameters of the individual Os particles in organosol were ∼1-3 nm, and the nominal lengths of the wires were ∼1-2 μm. The potentiality of the Os organosol was tested in two different applications: one is the catalytic hydrogenation of cyclohexene to cyclohexane and other is the surface enhanced Raman scattering (SERS) studies. The SERS study has been examined using MB as a Raman probe, and the EF value is found to be the highest in the case of Os organosol having aggregated wires (short size) compared to longer wires. The fast synthesis of Os organosol on DNA and their potential catalytic and SERS activity will be found to be very useful in the near future for the catalytic applications of various organic reactions and in the fields of sensors, electronic devices, and fuel cells.

本文言語English
ページ(範囲)19228-19238
ページ数11
ジャーナルIndustrial and Engineering Chemistry Research
53
49
DOI
出版ステータスPublished - 2014 12月 10
外部発表はい

ASJC Scopus subject areas

  • 化学 (全般)
  • 化学工学(全般)
  • 産業および生産工学

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