Oxidative coupling of methane using carbon dioxide in an electric field over La-ZrO2 catalyst at low external temperature

Kazumasa Oshima, Keisuke Tanaka, Tomohiro Yabe, Eiichi Kikuchi, Yasushi Sekine*

*この研究の対応する著者

研究成果: Article査読

34 被引用数 (Scopus)

抄録

Oxidative coupling of methane using carbon dioxide (CO2-OCM) as an oxidant was conducted over several La- and Zr-based catalysts in an electric field at low external temperature of 423 K. Higher catalytic activity was obtained than in a conventional catalytic reaction over 10 mol% lanthanum-doped zirconia (La-ZrO2) in the electric field. Although the catalytic activity for the CO2-OCM was low over the La-ZrO2 at 1173 K without the application of the electric field, the electric field promoted catalytic activity even at 423 K external temperature. We optimized the amount of doping-La in the La-ZrO2 system, and characterized the effect of doping-La with XRD measurement. From these examinations, 5 mol% La-ZrO 2 catalyst showed the highest activity. High catalytic activity was provided by the synergistic effect of the La-cation, tetragonal-ZrO2, and the electric field.

本文言語English
ページ(範囲)879-881
ページ数3
ジャーナルFuel
107
DOI
出版ステータスPublished - 2013

ASJC Scopus subject areas

  • 化学工学(全般)
  • 燃料技術
  • エネルギー工学および電力技術
  • 有機化学

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