Oxovanadium(III-V) mononuclear complexes and their linear assemblies bearing tetradentate Schiff base ligands: Structure and reactivity as multielectron redox catalysts

Eishun Tsuchida*, Kenichi Oyaizu

*この研究の対応する著者

研究成果: Article査読

106 被引用数 (Scopus)

抄録

This review summarizes the recent advances in the chemistry of oxovanadium(III-V) mononuclear complexes and their linear assemblies bearing tetradentate Schiff base ligands. Structural parameters of the oxovanadium assemblies are compiled, which reveal the preference of specific coordination geometries around vanadium atoms according to the valence state. Emphasis is placed on the catalysis of multielectron redox reactions by oxovanadium(IV) complexes which disproportionate to vanadium(III) and oxovanadium(V) complexes under suitable conditions. Their biological implications and synthetic applications are described.

本文言語English
ページ(範囲)213-228
ページ数16
ジャーナルCoordination Chemistry Reviews
237
1-2
DOI
出版ステータスPublished - 2003 2

ASJC Scopus subject areas

  • 物理化学および理論化学
  • 無機化学
  • 材料化学

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