Oxygen- and carbon monoxide-binding to a lipophilic diporphyrinatocopperiron complex solubilized in an aqueous medium with a micelle

Hiroyuki Nishide, Yukio Hashimoto, Hiromi Maeda, Eishun Tsuchida

研究成果: Article査読

4 被引用数 (Scopus)

抄録

A tetradecyl-substituted diporphyrinatocopperiron complex was synthesized and solubilized in an aqueous medium with a surfactant. Both the oxygen- and carbon monoxide-binding rate constants decreased due to the steric hindrance of the porphyrinatocopper cap, which brought about a reduced gas-binding affinity in comparison with other synthetic porphyrinatoiron complexes.

本文言語English
ページ(範囲)2963-2967
ページ数5
ジャーナルJournal of the Chemical Society, Dalton Transactions
12
DOI
出版ステータスPublished - 1987

ASJC Scopus subject areas

  • Chemistry(all)

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