Oxygen Vacancy Induced Room-Temperature Metal-Insulator Transition in Nickelate Films and Its Potential Application in Photovoltaics

Le Wang, Sibashisa Dash, Lei Chang, Lu You, Yaqing Feng, Xu He, Kui Juan Jin, Yang Zhou, Hock Guan Ong, Peng Ren, Shiwei Wang, Lang Chen, Junling Wang

研究成果: Article

45 引用 (Scopus)

抜粋

(Graph Presented) Oxygen vacancy is intrinsically coupled with magnetic, electronic, and transport properties of transition-metal oxide materials and directly determines their multifunctionality. Here, we demonstrate reversible control of oxygen content by postannealing at temperature lower than 300 °C and realize the reversible metal-insulator transition in epitaxial NdNiO3 films. Importantly, over 6 orders of magnitude in the resistance modulation and a large change in optical bandgap are demonstrated at room temperature without destroying the parent framework and changing the p-type conductive mechanism. Further study revealed that oxygen vacancies stabilized the insulating phase at room temperature is universal for perovskite nickelate films. Acting as electron donors, oxygen vacancies not only stabilize the insulating phase at room temperature, but also induce a large magnetization of ∼50 emu/cm3 due to the formation of strongly correlated Ni2+ t2g 6eg 2 states. The bandgap opening is an order of magnitude larger than that of the thermally driven metal-insulator transition and continuously tunable. Potential application of the newly found insulating phase in photovoltaics has been demonstrated in the nickelate-based heterojunctions. Our discovery opens up new possibilities for strongly correlated perovskite nickelates.

元の言語English
ページ(範囲)9769-9776
ページ数8
ジャーナルACS Applied Materials and Interfaces
8
発行部数15
DOI
出版物ステータスPublished - 2016 4 20
外部発表Yes

ASJC Scopus subject areas

  • Materials Science(all)

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    Wang, L., Dash, S., Chang, L., You, L., Feng, Y., He, X., Jin, K. J., Zhou, Y., Ong, H. G., Ren, P., Wang, S., Chen, L., & Wang, J. (2016). Oxygen Vacancy Induced Room-Temperature Metal-Insulator Transition in Nickelate Films and Its Potential Application in Photovoltaics. ACS Applied Materials and Interfaces, 8(15), 9769-9776. https://doi.org/10.1021/acsami.6b00650