抄録
Oxygenation of 3-methylindole was catalyzed by cobalt(II)phthalocyanine (Co(II)Pc) attached to polyorganosiloxane. The mechanism for the addition of oxygen to 3-methylindole was examined by means of the reaction rate determined from the amount of oxygen consumption. The reaction rate (V) was given as follows: V = K[3-methylindole] [Co(II)Pc][O2]. 3-Methylindole was concluded to be not only a substrate but also an oxidation inhibitor. The oxygenation was considered to proceed via a radical mechanism.
本文言語 | English |
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ページ(範囲) | 151-158 |
ページ数 | 8 |
ジャーナル | Journal of Molecular Catalysis |
巻 | 70 |
号 | 2 |
DOI | |
出版ステータス | Published - 1991 12月 1 |
ASJC Scopus subject areas
- 工学(全般)