Oxygenation of 3-methylindole catalyzed by cobalt(II) phthalocyanine attached to polyorganosiloxane Part 2. Mechanism for addition of oxygen to 3-methylindole

Nobukatsu Nemoto; Tetsuya Asakura; Katsuyuki Tobita; Yukihiko Ueno; Koji Ikeda; Nobuo Takamiya; Yasukazu Ohkatsu

doi:10.1016/0304-5102(91)80156-W

Oxygenation of 3-methylindole catalyzed by cobalt(II) phthalocyanine attached to polyorganosiloxane Part 2. Mechanism for addition of oxygen to 3-methylindole

Nobukatsu Nemoto, Tetsuya Asakura, Katsuyuki Tobita, Yukihiko Ueno, Koji Ikeda, Nobuo Takamiya^*, Yasukazu Ohkatsu

^*この研究の対応する著者

本庄高等学院

研究成果: Article › 査読

6 被引用数 (Scopus)

抄録

Oxygenation of 3-methylindole was catalyzed by cobalt(II)phthalocyanine (Co^(II)Pc) attached to polyorganosiloxane. The mechanism for the addition of oxygen to 3-methylindole was examined by means of the reaction rate determined from the amount of oxygen consumption. The reaction rate (V) was given as follows: V = K[3-methylindole] [Co^(II)Pc][O₂]. 3-Methylindole was concluded to be not only a substrate but also an oxidation inhibitor. The oxygenation was considered to proceed via a radical mechanism.

本文言語	English
ページ（範囲）	151-158
ページ数	8
ジャーナル	Journal of Molecular Catalysis
巻	70
号	2
DOI	https://doi.org/10.1016/0304-5102(91)80156-W
出版ステータス	Published - 1991 12月 1

ASJC Scopus subject areas

工学（全般）

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10.1016/0304-5102(91)80156-W

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abstract = "Oxygenation of 3-methylindole was catalyzed by cobalt(II)phthalocyanine (Co(II)Pc) attached to polyorganosiloxane. The mechanism for the addition of oxygen to 3-methylindole was examined by means of the reaction rate determined from the amount of oxygen consumption. The reaction rate (V) was given as follows: V = K[3-methylindole] [Co(II)Pc][O2]. 3-Methylindole was concluded to be not only a substrate but also an oxidation inhibitor. The oxygenation was considered to proceed via a radical mechanism.",

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AU - Nemoto, Nobukatsu

AU - Asakura, Tetsuya

AU - Tobita, Katsuyuki

AU - Ueno, Yukihiko

AU - Ikeda, Koji

AU - Takamiya, Nobuo

AU - Ohkatsu, Yasukazu

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AB - Oxygenation of 3-methylindole was catalyzed by cobalt(II)phthalocyanine (Co(II)Pc) attached to polyorganosiloxane. The mechanism for the addition of oxygen to 3-methylindole was examined by means of the reaction rate determined from the amount of oxygen consumption. The reaction rate (V) was given as follows: V = K[3-methylindole] [Co(II)Pc][O2]. 3-Methylindole was concluded to be not only a substrate but also an oxidation inhibitor. The oxygenation was considered to proceed via a radical mechanism.

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