Palladium-catalyzed reactions of alkenyloxiranes with carbon monoxide

Isao Shimizu, Takashi Maruyama, Toshiyuki Makuta, Akio Yamamoto

研究成果: Article査読

25 被引用数 (Scopus)

抄録

Reaction of alkenyloxiranes with carbon monoxide in the presence of palladium catalyst gives unsaturated esters, β-lactones, dienes, and allylic alcohols. The selectivity of the reaction depends on the nature of the alkenyloxiranes. Carbonylation pruducts were obtained in the reaction of terminal alkenyloxiranes and alkenyloxirans having electron-donating substituent, whereas carbonylation scarcely took place in the reaction of alkenyloxiranes having electron-withdrawing groups; dienes and allylic alcohols were produced instead of carbonylation products.

本文言語English
ページ(範囲)2135-2138
ページ数4
ジャーナルTetrahedron Letters
34
13
DOI
出版ステータスPublished - 1993 3 26

ASJC Scopus subject areas

  • 生化学
  • 有機化学
  • 創薬

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