Palladium-catalyzed rearrangement of allylic esters of acetoacetic acid to give γ,δ-unsaturated methyl ketones

Isao Shimizu; Toshiro Yamada; Jiro Tsuji

doi:10.1016/S0040-4039(00)77444-2

Palladium-catalyzed rearrangement of allylic esters of acetoacetic acid to give γ,δ-unsaturated methyl ketones

Isao Shimizu^*, Toshiro Yamada, Jiro Tsuji

^*この研究の対応する著者

研究成果: Article › 査読

205 被引用数 (Scopus)

抄録

Various allylic esters of acetoacetic acid undergo rearrangement to give γ,δ-unsaturated methyl ketones in high yields with elimination of carbon dioxide under mild conditions in the presence of catalytic amounts of Pd(OAc)₂ and PPh₃.

本文言語	English
ページ（範囲）	3199-3202
ページ数	4
ジャーナル	Tetrahedron Letters
巻	21
号	33
DOI	https://doi.org/10.1016/S0040-4039(00)77444-2
出版ステータス	Published - 1980

ASJC Scopus subject areas

生化学
有機化学
創薬

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10.1016/S0040-4039(00)77444-2

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title = "Palladium-catalyzed rearrangement of allylic esters of acetoacetic acid to give γ,δ-unsaturated methyl ketones",

abstract = "Various allylic esters of acetoacetic acid undergo rearrangement to give γ,δ-unsaturated methyl ketones in high yields with elimination of carbon dioxide under mild conditions in the presence of catalytic amounts of Pd(OAc)2 and PPh3.",

author = "Isao Shimizu and Toshiro Yamada and Jiro Tsuji",

year = "1980",

doi = "10.1016/S0040-4039(00)77444-2",

language = "English",

volume = "21",

pages = "3199--3202",

journal = "Tetrahedron Letters",

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T1 - Palladium-catalyzed rearrangement of allylic esters of acetoacetic acid to give γ,δ-unsaturated methyl ketones

AU - Shimizu, Isao

AU - Yamada, Toshiro

AU - Tsuji, Jiro

PY - 1980

Y1 - 1980

N2 - Various allylic esters of acetoacetic acid undergo rearrangement to give γ,δ-unsaturated methyl ketones in high yields with elimination of carbon dioxide under mild conditions in the presence of catalytic amounts of Pd(OAc)2 and PPh3.

AB - Various allylic esters of acetoacetic acid undergo rearrangement to give γ,δ-unsaturated methyl ketones in high yields with elimination of carbon dioxide under mild conditions in the presence of catalytic amounts of Pd(OAc)2 and PPh3.

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U2 - 10.1016/S0040-4039(00)77444-2

DO - 10.1016/S0040-4039(00)77444-2

M3 - Article

AN - SCOPUS:0006425658

SN - 0040-4039

VL - 21

SP - 3199

EP - 3202

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 33

ER -

Palladium-catalyzed rearrangement of allylic esters of acetoacetic acid to give γ,δ-unsaturated methyl ketones

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