Palladium-catalyzed ring-opening reactions of 1-acetyl-4-vinyl-2-azetidinones and 1-sulfonyl-2-vinylazetidines. Role of intramolecular participation of amide anion

Akiharu Satake, Hideo Ishii, Isao Shimizu, Yoichi Inoue, Hajime Hasegawa, Akio Yamamoto

研究成果: Article

16 引用 (Scopus)

抜粋

Ring opening reactions of 1-acetyl-4-vinyl-2-azetidinones in the presence of palladium(0)-n-Bu3P catalyst gave 2,4-pentadienamides in good yields, whereas 2-substituted-1,3-dienes were produced by the reaction of 1-sulfonyl-2-vinyl-2-methylazetidines. Ring opening dimerization took place to give 1,7-ditrifluoromethanesulfonyl-1,7-diazacyclododecane in the reaction of 1-trifluoromethanesulfonyl-2-vinylazetidine.

元の言語English
ページ(範囲)5331-5340
ページ数10
ジャーナルTetrahedron
51
発行部数18
DOI
出版物ステータスPublished - 1995 5 1

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ASJC Scopus subject areas

  • Biochemistry
  • Organic Chemistry
  • Drug Discovery

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