Pd-catalyzed C4-Dearomative Allylation of Benzyl Ammoniums with Allyltributylstannane

Yuki Kayashima, Masaaki Komatsuda, Kei Muto, Junichiro Yamaguchi*

*この研究の対応する著者

研究成果: Article査読

7 被引用数 (Scopus)

抄録

A dearomative C4-allylation of benzyl ammoniums with allyltributylstannane by a palladium catalysis is described. A triarylphosphine-ligated palladium catalyst, which is capable of cleaving benzylic CN bonds, realized facile dearomative reactions with C4 selectivity. Combined with precedented C2- A nd C3-selective functionalizations of benzyl amine derivatives, the present reaction can provide a new synthetic option for the synthesis of multi-substituted alicyclic compounds as well as aromatic compounds.

本文言語English
ページ(範囲)836-839
ページ数4
ジャーナルChemistry Letters
49
7
DOI
出版ステータスPublished - 2020 7

ASJC Scopus subject areas

  • 化学 (全般)

フィンガープリント

「Pd-catalyzed C4-Dearomative Allylation of Benzyl Ammoniums with Allyltributylstannane」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

引用スタイル