@article{527328ae4f4e4f19a0e305b1e96f8eeb,
title = "Pd-catalyzed C4-Dearomative Allylation of Benzyl Ammoniums with Allyltributylstannane",
abstract = "A dearomative C4-allylation of benzyl ammoniums with allyltributylstannane by a palladium catalysis is described. A triarylphosphine-ligated palladium catalyst, which is capable of cleaving benzylic CN bonds, realized facile dearomative reactions with C4 selectivity. Combined with precedented C2- A nd C3-selective functionalizations of benzyl amine derivatives, the present reaction can provide a new synthetic option for the synthesis of multi-substituted alicyclic compounds as well as aromatic compounds.",
keywords = "Benzyl ammoniums, Dearomatization, Palladium catalyst",
author = "Yuki Kayashima and Masaaki Komatsuda and Kei Muto and Junichiro Yamaguchi",
note = "Funding Information: This work was supported by JSPS KAKENHI Grant Number JP19H02726 (to J.Y.), JP18H04661 (Hybrid Catalysis), JP19K15573, and The SATOMI Scholarship Foundation (to K.M.). The Materials Characterization Central Laboratory at Waseda University is acknowledged for the support of HRMS measurement. Publisher Copyright: {\textcopyright} 2020 Chemical Society of Japan. All rights reserved.",
year = "2020",
month = jul,
doi = "10.1246/cl.200216",
language = "English",
volume = "49",
pages = "836--839",
journal = "Chemistry Letters",
issn = "0366-7022",
publisher = "Chemical Society of Japan",
number = "7",
}