Pd-Catalyzed Dearomative Three-Component Reaction of Bromoarenes with Diazo Compounds and Allylborates

Masaaki Komatsuda, Hiroki Kato, Kei Muto, Junichiro Yamaguchi

研究成果: Article

2 引用 (Scopus)

抄録

A catalytic dearomative three-component reaction of bromoarenes with TMS-diazomethane and allyl borate was developed. The key of this assembling reaction is the use of a diazo compound to generate a Pd-π-benzyl intermediate through a Pd-carbene species. This method allowed for a dearomative functionalization, using arenes as limiting reagents. Heteroaryl bromides were also applicable to give dearomatized structures under the reaction conditions.

元の言語English
ページ(範囲)8991-8995
ページ数5
ジャーナルACS Catalysis
9
発行部数10
DOI
出版物ステータスPublished - 2019 1 1

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Diazomethane
Borates
Bromides
carbene

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)

これを引用

Pd-Catalyzed Dearomative Three-Component Reaction of Bromoarenes with Diazo Compounds and Allylborates. / Komatsuda, Masaaki; Kato, Hiroki; Muto, Kei; Yamaguchi, Junichiro.

:: ACS Catalysis, 巻 9, 番号 10, 01.01.2019, p. 8991-8995.

研究成果: Article

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