Pd-Catalyzed Dearomative Three-Component Reaction of Bromoarenes with Diazo Compounds and Allylborates

Masaaki Komatsuda, Hiroki Kato, Kei Muto, Junichiro Yamaguchi

研究成果: Article査読

14 被引用数 (Scopus)

抄録

A catalytic dearomative three-component reaction of bromoarenes with TMS-diazomethane and allyl borate was developed. The key of this assembling reaction is the use of a diazo compound to generate a Pd-π-benzyl intermediate through a Pd-carbene species. This method allowed for a dearomative functionalization, using arenes as limiting reagents. Heteroaryl bromides were also applicable to give dearomatized structures under the reaction conditions.

本文言語English
ページ(範囲)8991-8995
ページ数5
ジャーナルACS Catalysis
9
10
DOI
出版ステータスPublished - 2019 10 4

ASJC Scopus subject areas

  • 触媒
  • 化学 (全般)

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