Pd-Catalyzed Denitrative Intramolecular C-H Arylation

Kitty K. Asahara, Toshimasa Okita, Ami N. Saito, Kei Muto, Yoshiaki Nakao, Junichiro Yamaguchi

研究成果: Article

1 引用 (Scopus)

抄録

A Pd-catalyzed intramolecular C-H arylation of nitroarenes has been developed. Nitroarenes bearing tethered aryl groups at the ortho-position can be readily prepared in one step from 2-halonitroarenes by a nucleophilic aromatic substitution (SNAr). Under Pd/BrettPhos catalysis, activations of the C-NO2 bond as well as the C-H bond on arenes generated the corresponding biaryl linkage in moderate to excellent yields.

元の言語English
ページ(範囲)4721-4724
ページ数4
ジャーナルOrganic Letters
21
発行部数12
DOI
出版物ステータスPublished - 2019 6 21

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Bearings (structural)
Catalysis
linkages
catalysis
Substitution reactions
Chemical activation
activation
substitutes

ASJC Scopus subject areas

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry

これを引用

Pd-Catalyzed Denitrative Intramolecular C-H Arylation. / Asahara, Kitty K.; Okita, Toshimasa; Saito, Ami N.; Muto, Kei; Nakao, Yoshiaki; Yamaguchi, Junichiro.

:: Organic Letters, 巻 21, 番号 12, 21.06.2019, p. 4721-4724.

研究成果: Article

Asahara, KK, Okita, T, Saito, AN, Muto, K, Nakao, Y & Yamaguchi, J 2019, 'Pd-Catalyzed Denitrative Intramolecular C-H Arylation', Organic Letters, 巻. 21, 番号 12, pp. 4721-4724. https://doi.org/10.1021/acs.orglett.9b01593
Asahara, Kitty K. ; Okita, Toshimasa ; Saito, Ami N. ; Muto, Kei ; Nakao, Yoshiaki ; Yamaguchi, Junichiro. / Pd-Catalyzed Denitrative Intramolecular C-H Arylation. :: Organic Letters. 2019 ; 巻 21, 番号 12. pp. 4721-4724.
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