Pd-catalyzed reductive cleavage of alkyl aryl sulfides with triethylsilane that is accelerated by trialkylsilyl chloride

Takehiko Matsumura, Takashi Niwa, Masahisa Nakada

    研究成果: Article

    22 引用 (Scopus)

    抄録

    The palladium-catalyzed reductive cleavage of alkyl aryl sulfides to afford the corresponding arenes in high yield, which is both accelerated and exhibits increased functional group selectivity in the presence of TMSCl, is described. This ligand-free reaction features mild conditions, easy operation, use of readily available reagents, and high functional group selectivity.

    元の言語English
    ページ(範囲)4313-4316
    ページ数4
    ジャーナルTetrahedron Letters
    53
    発行部数33
    DOI
    出版物ステータスPublished - 2012 8 15

    Fingerprint

    Palladium
    Sulfides
    Functional groups
    Chlorides
    Ligands
    triethylsilane

    ASJC Scopus subject areas

    • Biochemistry
    • Organic Chemistry
    • Drug Discovery

    これを引用

    Pd-catalyzed reductive cleavage of alkyl aryl sulfides with triethylsilane that is accelerated by trialkylsilyl chloride. / Matsumura, Takehiko; Niwa, Takashi; Nakada, Masahisa.

    :: Tetrahedron Letters, 巻 53, 番号 33, 15.08.2012, p. 4313-4316.

    研究成果: Article

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    AU - Niwa, Takashi

    AU - Nakada, Masahisa

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    KW - Alkyl aryl sulfide

    KW - Pd-catalyzed

    KW - Reductive cleavage

    KW - Trialkylsilyl chloride

    KW - Triethylsilane

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