Perfluorooctanesulfonic acid detection using molecularly imprinted polyaniline on a paper substrate

Ting Yen Chi, Zheyuan Chen, Jun Kameoka*

*この研究の対応する著者

研究成果: Article査読

6 被引用数 (Scopus)

抄録

Perfluorinated compounds like perfluorooctanesulfonic acid (PFOS) are synthetic water pollutants and have accumulated in environments for decades, causing a serious global health issue. Conventional assays rely on liquid chromatography and mass spectroscopy that are very expensive and complicated and thus limit the large-scale monitoring of PFOS in wastewater. To achieve low-cost and accurate detection of PFOS, we designed a paper-based sensor with molecularly imprinted polyaniline electrodes that have recognition sites specific to PFOS. The calibration curve of resistivity ratios as a function of PFOS concentrations has a linear range from 1 to 100 ppt with a coefficient of determination of 0.995. The estimated limit of detection is 1.02 ppt. We also investigated attenuated total reflectance Fourier-transform infrared spectroscopy (ATR-FTIR) and X-ray photoelectron spectroscopy (XPS) spectra of the surface of the polyaniline (PANI) electrodes to propose the potential recognition sites in polyaniline matrix and the detection mechanism. This electrical paper sensor with low cost and excellent sensitivity and selectivity provides the potential for large-scale monitoring of wastewater.

本文言語English
論文番号7301
ページ(範囲)1-15
ページ数15
ジャーナルSensors (Switzerland)
20
24
DOI
出版ステータスPublished - 2020 12月 2
外部発表はい

ASJC Scopus subject areas

  • 分析化学
  • 情報システム
  • 生化学
  • 原子分子物理学および光学
  • 器械工学
  • 電子工学および電気工学

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