Perovskite/TiO2 Interface Passivation Using Poly(vinylcarbazole) and Fullerene for the Photovoltaic Conversion Efficiency of 21%

Wataru Okada, Takeo Suga, Kenichi Oyaizu, Hiroshi Segawa, Hiroyuki Nishide*

*この研究の対応する著者

研究成果: Article査読

20 被引用数 (Scopus)

抄録

Poly(vinylcarbazole) (PVCz) dispersed the typical fullerene derivative, PCBM, well in its solution, which was then coated onto a mesoporous titanium oxide (TiO2) layer. PVCz served as a scaffold to fix PCBM homogeneously and to prevent its elution out upon the following perovskite layer formation. A series of perovskite cells were fabricated upon the PVCz/PCBM-modified TiO2 layer. Many of the cells were characterized by a photovoltaic conversion efficiency of >20%, and the top cells had an efficiency of 21.1% (with an average of 21.0%). Fluorescence decay from the perovskite layer of the cell was unchanged with the PVCz/PCBM modification, suggesting an efficient charge transport to the electron-transporting layers. On the other hand, the PVCz/PCBM modification or passivation significantly reduced electroluminescence intensity under an inverse bias application, supporting an efficient suppression of carrier recombination at the TiO2 and perovskite interface.

本文言語English
ページ(範囲)2848-2853
ページ数6
ジャーナルACS Applied Energy Materials
2
4
DOI
出版ステータスPublished - 2019 4 22

ASJC Scopus subject areas

  • 化学工学(その他)
  • エネルギー工学および電力技術
  • 電気化学
  • 電子工学および電気工学
  • 材料化学

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