PH-responsive cellulose nanocrystal gels and nanocomposites

Amanda E. Way, Lorraine Hsu, Kadhiravan Shanmuganathan, Christoph Weder, Stuart J. Rowan

研究成果: Article

145 引用 (Scopus)

抜粋

We show that functionalization of the surface of cellulose nanocrystals (CNCs) with either carboxylic acid (CNC-CO2H) or amine (CNC-NH 2) moieties renders the CNCs pHresponsive. At low pH, where the amine groups are protonated, CNC-NH2 forms aqueous dispersions in water on account of electrostatic repulsions of the ammonium moieties inhibiting aggregation. However, a transition to hydrogels is observed at higher pH where the CNC-NH2 are neutral and the attractive forces based on hydrogen bonding dominate. The opposite behavior is observed for CNC-CO2H, which are dispersible at high pH and form gels in an acidic environment. We further show that these pH-responsive CNCs can be incorporated into a poly(vinyl acetate) matrix to yield mechanically adaptive pH-responsive nanocomposite films.

元の言語English
ページ(範囲)1001-1006
ページ数6
ジャーナルACS Macro Letters
1
発行部数8
DOI
出版物ステータスPublished - 2012
外部発表Yes

    フィンガープリント

ASJC Scopus subject areas

  • Organic Chemistry
  • Materials Chemistry
  • Polymers and Plastics
  • Inorganic Chemistry

これを引用

Way, A. E., Hsu, L., Shanmuganathan, K., Weder, C., & Rowan, S. J. (2012). PH-responsive cellulose nanocrystal gels and nanocomposites. ACS Macro Letters, 1(8), 1001-1006. https://doi.org/10.1021/mz3003006