Phase transition in ferroelectric SrBi2Ta2O9 thin films with change of heat-treatment temperature

Tetsuya Osaka*, Akira Sakakibara, Tomonori Seki, Sachiko Ono, Ichiro Koiwa, Akira Hashimoto


研究成果: Article査読

52 被引用数 (Scopus)


Changes in the composition and the crystal structure of micro-grains have been studied using transmission electron microscopy (TEM) and energy dispersive X-ray microanalysis in order to clarify the phase formation of ferroelectric SrBi2Ta2O9 (SBT) with heat-treatment at 650-750°C. Micrograins crystallized at 650°C begin to change to bismuth-layer-structure-family (BLSF) grains at temperatures exceeding 700°C, and form pure-BLSF phase grains at 800°C. Hence, a micrograins phase exists in thin films at 650-750°C and we determined that the bismuth composition in these grains decreases. Using selected diffraction and high-resolution TEM, we found that a pyrochlore phase was formed in the bismuth-poor micrograins that were heat treated at 750°C. The formation of pyrochlore made pure-phase BLSF difficult to obtain.

ジャーナルJapanese Journal of Applied Physics, Part 1: Regular Papers and Short Notes and Review Papers
出版ステータスPublished - 1998 2 1

ASJC Scopus subject areas

  • 工学(全般)
  • 物理学および天文学(全般)


「Phase transition in ferroelectric SrBi<sub>2</sub>Ta<sub>2</sub>O<sub>9</sub> thin films with change of heat-treatment temperature」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。