Phenanthro[9,10- a ]corannulene by one-step annulative π-extension of corannulene

Kenta Kato, Yasutomo Segawa*, Kenichiro Itami

*この研究の対応する著者

研究成果: Article査読

28 被引用数 (Scopus)

抄録

The one-step π-extension of corannulene was achieved using a palladium-catalyzed C-H coupling reaction. The X-ray crystal structure and photophysical properties of the thus formed phenanthro[9,10-a]corannulene (1) were investigated, and the structural properties of 1 were examined by density functional theory calculations. In contrast to dibenzo[g,p]chrysene, the most stable structure of 1 was a butterfly-shaped structure, resulting from the bowl-shaped distortion of the corannulene moiety.

本文言語English
ページ(範囲)329-333
ページ数5
ジャーナルCanadian Journal of Chemistry
95
3
DOI
出版ステータスPublished - 2017
外部発表はい

ASJC Scopus subject areas

  • 触媒
  • 化学 (全般)
  • 有機化学

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