Intercalation compounds of layered niobates HA2Nb3O10 (A = Ca, Sr), which have perovskite-type oxide layers, with methylviologen dications have been synthesized. Although the two intercalation compounds were structurally similar, they exhibited different photochemical behavior. UV irradiation of the MV2+-intercalates caused electron transfer from the host to methylviologen dications in the HCa2Nb3O10 system, whereas photoreduction of Nb ions in the host lattice was observed in the HSr2Nb3O10 system.
ASJC Scopus subject areas
- 化学 (全般)