Photoisomerization of azobenzene in the interlayer space of magadiite

Makoto Ogawa*

*この研究の対応する著者

研究成果: Article査読

46 被引用数 (Scopus)

抄録

The intercalation of a cationic azobenzene derivative into the interlayer space of magadiite was conducted by the ion exchange reactions between magadiite and p-[2-(2-hydroxyethyldimethylammonio)ethoxy]azobenzene bromide. X-Ray diffraction and elemental analysis confirmed the formation of the p-[2-(2-hydroxyethyldimethylammonio)ethoxy]azobenzene magadiite intercalation compound. The spectral properties, as well as the X-ray diffraction results, reveal that the adsorbed azo dye cations form head-to-head aggregates in the interlayer space. The intercalation compound exhibited a novel photomechanical effect; the basal spacing changed reversibly upon photoisomerization of the intercalated azo dye.

本文言語English
ページ(範囲)3304-3307
ページ数4
ジャーナルJournal of Materials Chemistry
12
11
DOI
出版ステータスPublished - 2002 11 1

ASJC Scopus subject areas

  • 物理化学および理論化学
  • 材料化学
  • 材料科学(全般)

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