Photoregulation of retro-diels alder reaction at the Center of Polymer Chains

Jumpei Kida, Keiichi Imato, Raita Goseki, Masakazu Morimoto, Hideyuki Otsuka*

*この研究の対応する著者

研究成果: Article査読

7 被引用数 (Scopus)

抄録

Photoregulation of polymer chain scission based on a DielsAlder (DA) adduct containing diarylethene (DAE) was investigated. Poly(ϵ-caprolactone) with a DA adduct conjugated with DAE skeleton (DAE/DA) at the center of the chain was synthesized by ring-opening living cationic polymerization of ϵ-caprolactone, initiating from diol-type DAE/DA, and its chain scission via thermally induced retro-DA reaction was successfully controlled by photoisomerization of DAE.

本文言語English
ページ(範囲)992-994
ページ数3
ジャーナルChemistry Letters
46
7
DOI
出版ステータスPublished - 2017
外部発表はい

ASJC Scopus subject areas

  • 化学 (全般)

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