Poly(β-thioesters) containing monodisperse oxamide hard segments using a chemoselective thiol-Michael addition reaction

Nicholas G. Moon, Ryan J. Mondschein, Timothy Edward Long*

*この研究の対応する著者

研究成果: Article査読

12 被引用数 (Scopus)

抄録

The inherent chemoselectivity of the thiol-Michael addition reaction enabled the synthesis of segmented copolymers using a one-pot, one-step procedure. The enhanced reactivity of a thiol towards an acrylate over a methacrylate generated thiol-terminated soft segment oligomers in the presence of bis-oxamide dimethacrylate hard segment monomers, furnishing segmented copolymers containing monodisperse hard segments after in situ chain extension. Thermomechanical characterization revealed extended plateau regions for all compositions with segmented and unsegmented copolymer analogs displaying similar plateau moduli, glass transition temperatures, and flow temperatures. Preliminary morphological analysis indicated a degree of undesired phase-mixing as a result of hydrogen-bond acceptors in the soft segment. The effectiveness of the bis-oxamide hydrogen-bonding motif allowed for sufficient phase separation to provide extended plateau regions for all samples as observed with dynamic mechanical analysis.

本文言語English
ページ(範囲)2598-2608
ページ数11
ジャーナルPolymer Chemistry
8
17
DOI
出版ステータスPublished - 2017 5月 7
外部発表はい

ASJC Scopus subject areas

  • バイオエンジニアリング
  • 生化学
  • 生体医工学
  • ポリマーおよびプラスチック
  • 有機化学

フィンガープリント

「Poly(β-thioesters) containing monodisperse oxamide hard segments using a chemoselective thiol-Michael addition reaction」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

引用スタイル