All-acrylic block copolymer precursors can be synthesized via anionic techniques demonstrating predictable molecular weights and narrow molecular weight distributions. Poly(2-ethylhexyl methacrylate) can possess such desirable properties as a low glass transition temperature, alkane solubility, and a hydrophobic character. Quantitative hydrolysis of poly(t-butyl methacrylate) blocks allows for very distinct hydrophobic-hydrophilic block copolymers. The derived ion-containing block copolymers will serve as excellent model systems for the elucidation of structure-property relationships. It is believed that the extent and mechanisms of coulombic aggregation will be significantly different than the corresponding random systems.
|ジャーナル||American Chemical Society, Polymer Preprints, Division of Polymer Chemistry|
|出版ステータス||Published - 1987 8月 1|
|イベント||Polym Prepr -Pap Presented at the New Orleans, LA Meet - New Orleans, LA, USA|
継続期間: 1987 8月 30 → 1987 9月 4
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