In this report, we describe the fabrication and photo-induced alignment of ultrathin films of small molecular azobenzene dyes and polyelectrolytes using the alternate polyelectrolyte deposition (APD) technique. The molecular self-assembly process were investigated by QCM, ellipsometry, UV-vis spectroscopy, X-ray reflectometry, and other surface sensitive spectroscopic and microscopic methods to correlate with film formation parameters. The importance of layer ordering and dye aggregation phenomena is emphasized. We then utilized polarized UV-light to induce photo-alignment of these ultrathin films and observed high anisotropies dependent on the dye, layer preparation and thickness. Fabrication of hybrid LC cells using a nematic LC reveal that in-plane homogeneous alignment is influenced by the anisotropy of the dye aggregates.
|ジャーナル||Materials Research Society Symposium - Proceedings|
|出版物ステータス||Published - 1999|
ASJC Scopus subject areas
- Electronic, Optical and Magnetic Materials