Poly(phenylvinylene) and poly(phenylenevinylene) with tear-butyInitroxide as a built-in radical group were synthesized. Precursor polymers were obtained by the polymerization of the corresponding acetylene and styrene derivatives by Rh and Pd catalysts. They were soluble in common soivents and their chemical Oxidation under moderate condition gave the corresponding polyradicals.
|ジャーナル||Molecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals|
|出版ステータス||Published - 1993 8 1|
ASJC Scopus subject areas
- Materials Science(all)
- Condensed Matter Physics