Poly(thiaheterohelicene): A stiff conjugated helical polymer comprised of fused benzothiophene rings

Tomokazu Iwasaki, Yusaku Kohinata, Hiroyuki Nishide

研究成果: Article

58 引用 (Scopus)

抄録

(Chemical Equation Presented) A novel helical aromatic polymer comprised of fused benzothiophene rings, poly(thiaheterohelicene), was synthesized via an intramolecular ring-closing reaction with a controlled helicity to one-sided bias. The synthetic helicity control involved the induction of the helical conformation and its fixation. The ladder polymer showed both an extended π-conjugation and planarity and a very stiff helical structure.

元の言語English
ページ(範囲)755-758
ページ数4
ジャーナルOrganic Letters
7
発行部数5
DOI
出版物ステータスPublished - 2005 3 3

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Aromatic polymers
Ladders
Conformations
Polymers
rings
polymers
closing
conjugation
ladders
induction
benzothiophene

ASJC Scopus subject areas

  • Molecular Medicine

これを引用

Poly(thiaheterohelicene) : A stiff conjugated helical polymer comprised of fused benzothiophene rings. / Iwasaki, Tomokazu; Kohinata, Yusaku; Nishide, Hiroyuki.

:: Organic Letters, 巻 7, 番号 5, 03.03.2005, p. 755-758.

研究成果: Article

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