Poly(thiaheterohelicene): A stiff conjugated helical polymer comprised of fused benzothiophene rings

Tomokazu Iwasaki, Yusaku Kohinata, Hiroyuki Nishide*

*この研究の対応する著者

研究成果: Article査読

62 被引用数 (Scopus)

抄録

(Chemical Equation Presented) A novel helical aromatic polymer comprised of fused benzothiophene rings, poly(thiaheterohelicene), was synthesized via an intramolecular ring-closing reaction with a controlled helicity to one-sided bias. The synthetic helicity control involved the induction of the helical conformation and its fixation. The ladder polymer showed both an extended π-conjugation and planarity and a very stiff helical structure.

本文言語English
ページ(範囲)755-758
ページ数4
ジャーナルOrganic Letters
7
5
DOI
出版ステータスPublished - 2005 3 3

ASJC Scopus subject areas

  • 分子医療

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