Pre-melting structure transformation of water clusters in nanoporous molecular crystals

Makoto Tadokoro; Yuki Ohata; Yuriko Shimazaki; Kyosuke Isoda; Tomoaki Sugaya

doi:10.1002/cphc.201200414

Pre-melting structure transformation of water clusters in nanoporous molecular crystals

Makoto Tadokoro^*, Yuki Ohata, Yuriko Shimazaki, Kyosuke Isoda, Tomoaki Sugaya

^*この研究の対応する著者

研究成果: Article › 査読

5 被引用数 (Scopus)

抄録

Water nanotubes are one-dimensional channels of water clusters that exist in nanoporous H-bonded metal-coordination crystals of cobalt(III) complexes and trimesate. It is shown by X-ray crystallography that the pre-melting endothermic peak observed in the ascending differential scanning calorimetry curve results from partial movement of water molecules of the frozen state as a result of a structural transition (see picture).

本文言語	English
ページ（範囲）	3267-3270
ページ数	4
ジャーナル	ChemPhysChem
巻	13
号	14
DOI	https://doi.org/10.1002/cphc.201200414
出版ステータス	Published - 2012 10月 8
外部発表	はい

ASJC Scopus subject areas

物理化学および理論化学
原子分子物理学および光学

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10.1002/cphc.201200414

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abstract = "Water nanotubes are one-dimensional channels of water clusters that exist in nanoporous H-bonded metal-coordination crystals of cobalt(III) complexes and trimesate. It is shown by X-ray crystallography that the pre-melting endothermic peak observed in the ascending differential scanning calorimetry curve results from partial movement of water molecules of the frozen state as a result of a structural transition (see picture).",

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author = "Makoto Tadokoro and Yuki Ohata and Yuriko Shimazaki and Kyosuke Isoda and Tomoaki Sugaya",

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T1 - Pre-melting structure transformation of water clusters in nanoporous molecular crystals

AU - Tadokoro, Makoto

AU - Ohata, Yuki

AU - Shimazaki, Yuriko

AU - Isoda, Kyosuke

AU - Sugaya, Tomoaki

PY - 2012/10/8

Y1 - 2012/10/8

N2 - Water nanotubes are one-dimensional channels of water clusters that exist in nanoporous H-bonded metal-coordination crystals of cobalt(III) complexes and trimesate. It is shown by X-ray crystallography that the pre-melting endothermic peak observed in the ascending differential scanning calorimetry curve results from partial movement of water molecules of the frozen state as a result of a structural transition (see picture).

AB - Water nanotubes are one-dimensional channels of water clusters that exist in nanoporous H-bonded metal-coordination crystals of cobalt(III) complexes and trimesate. It is shown by X-ray crystallography that the pre-melting endothermic peak observed in the ascending differential scanning calorimetry curve results from partial movement of water molecules of the frozen state as a result of a structural transition (see picture).

KW - crystal growth

KW - phase transitions

KW - porous materials

KW - water clusters

KW - x-ray diffraction

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JO - ChemPhysChem

JF - ChemPhysChem

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Pre-melting structure transformation of water clusters in nanoporous molecular crystals

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