Precise control of band filling in Na xCoO 2

Daisuke Yoshizumi*, Yuji Muraoka, Yoshihiko Okamoto, Yoko Kiuchi, Jun Ichi Yamaura, Masahito Mochizuki, Masao Ogata, Zenji Hiroi


研究成果: Article査読

29 被引用数 (Scopus)


Electronic properties of the sodium cobaltate Na xCoO 2 are systematically studied through a precise control of band filling. Resistivity, magnetic susceptibility and specific heat measurements are carried out on a series of high-quality polycrystalline samples prepared at 200 °C with Na content in a wide range of 0:35 ≤ x ≤ 0:70. It is found that dramatic changes in electronic properties take place at a critical Na concentration x* that lies between 0.58 and 0.59, which separates a Pauli paramagnetic and a Curie-Weiss metals. It is suggested that at x* the Fermi level touches the bottom of the a 1g band at the Γ point, leading to a crucial change in the density of states across x* and the emergence of a small electron pocket around the Γ point for x > x*.

ジャーナルjournal of the physical society of japan
出版ステータスPublished - 2007 6月

ASJC Scopus subject areas

  • 物理学および天文学(全般)


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