Preparation and properties of nylon 6/carboxylic silica nanocomposites via in situ polymerization

Lala Zhang, Yuzi Xiong, Encai Ou, Zhongming Chen, Yuanqin Xiong, Weijian Xu

研究成果: Article

10 引用 (Scopus)

抄録

Nylon 6/carboxylic acid-functionalized silica nanoparticles (SiO 2-COOH) nanocomposites were prepared by in situ polymerization of caprolactam in the presence of SiO2-COOH. The aim of this work was to study the effect of carboxylic silica on the properties of the nylon 6 through the interfacial interactions between the SiO2-COOH nanoparticles and the nylon 6 matrix. For comparison, pure nylon 6, nylon 6/SiO2 (unmodified) and nylon 6/amino-functionalized SiO2 (SiO 2-NH2) were also prepared via the same method. Fourier transform infrared spectrometer (FTIR) spectroscopy was used to evaluate the structure of SiO2-COOH and nylon 6/SiO2-COOH. The results from thermal gravimetric analysis (TGA) indicated that decomposition temperatures of nylon 6/SiO2-COOH nanocomposites at the 5 wt % of the total weight loss were higher than the pure nylon 6. Differential scanning calorimeter (DSC) studies showed that the melting point (Tm) and degree of crystallinity (Xc) of nylon 6/SiO2-COOH were lower than the pure nylon 6. Mechanical properties results of the nanocomposites showed that nylon 6 with incorporation of SiO2-COOH had better mechanical properties than that of pure nylon 6, nylon 6/SiO2, and nylon 6/SiO2-NH2. The morphology of SiO2, SiO2-NH2, and SiO2-COOH nanoparticles in nylon 6 matrix was observed using SEM measurements. The results revealed that the dispersion of SiO2-COOH nanoparticles in nylon 6 matrix was better than SiO2 and SiO2-NH2 nanoparticles.

元の言語English
ページ(範囲)1316-1324
ページ数9
ジャーナルJournal of Applied Polymer Science
122
発行部数2
DOI
出版物ステータスPublished - 2011 10 15
外部発表Yes

Fingerprint

Silicon Dioxide
Nanocomposites
Silica
Polymerization
Nanoparticles
Mechanical properties
Infrared spectrometers
Gravimetric analysis
Calorimeters
Carboxylic acids
Melting point
Fourier transforms
nylon 6
Spectroscopy
Decomposition
Scanning
Scanning electron microscopy
Caprolactam
Temperature
Carboxylic Acids

ASJC Scopus subject areas

  • Materials Chemistry
  • Polymers and Plastics
  • Surfaces, Coatings and Films
  • Chemistry(all)

これを引用

Preparation and properties of nylon 6/carboxylic silica nanocomposites via in situ polymerization. / Zhang, Lala; Xiong, Yuzi; Ou, Encai; Chen, Zhongming; Xiong, Yuanqin; Xu, Weijian.

:: Journal of Applied Polymer Science, 巻 122, 番号 2, 15.10.2011, p. 1316-1324.

研究成果: Article

Zhang, Lala ; Xiong, Yuzi ; Ou, Encai ; Chen, Zhongming ; Xiong, Yuanqin ; Xu, Weijian. / Preparation and properties of nylon 6/carboxylic silica nanocomposites via in situ polymerization. :: Journal of Applied Polymer Science. 2011 ; 巻 122, 番号 2. pp. 1316-1324.
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abstract = "Nylon 6/carboxylic acid-functionalized silica nanoparticles (SiO 2-COOH) nanocomposites were prepared by in situ polymerization of caprolactam in the presence of SiO2-COOH. The aim of this work was to study the effect of carboxylic silica on the properties of the nylon 6 through the interfacial interactions between the SiO2-COOH nanoparticles and the nylon 6 matrix. For comparison, pure nylon 6, nylon 6/SiO2 (unmodified) and nylon 6/amino-functionalized SiO2 (SiO 2-NH2) were also prepared via the same method. Fourier transform infrared spectrometer (FTIR) spectroscopy was used to evaluate the structure of SiO2-COOH and nylon 6/SiO2-COOH. The results from thermal gravimetric analysis (TGA) indicated that decomposition temperatures of nylon 6/SiO2-COOH nanocomposites at the 5 wt {\%} of the total weight loss were higher than the pure nylon 6. Differential scanning calorimeter (DSC) studies showed that the melting point (Tm) and degree of crystallinity (Xc) of nylon 6/SiO2-COOH were lower than the pure nylon 6. Mechanical properties results of the nanocomposites showed that nylon 6 with incorporation of SiO2-COOH had better mechanical properties than that of pure nylon 6, nylon 6/SiO2, and nylon 6/SiO2-NH2. The morphology of SiO2, SiO2-NH2, and SiO2-COOH nanoparticles in nylon 6 matrix was observed using SEM measurements. The results revealed that the dispersion of SiO2-COOH nanoparticles in nylon 6 matrix was better than SiO2 and SiO2-NH2 nanoparticles.",
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AU - Xiong, Yuzi

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AU - Xiong, Yuanqin

AU - Xu, Weijian

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N2 - Nylon 6/carboxylic acid-functionalized silica nanoparticles (SiO 2-COOH) nanocomposites were prepared by in situ polymerization of caprolactam in the presence of SiO2-COOH. The aim of this work was to study the effect of carboxylic silica on the properties of the nylon 6 through the interfacial interactions between the SiO2-COOH nanoparticles and the nylon 6 matrix. For comparison, pure nylon 6, nylon 6/SiO2 (unmodified) and nylon 6/amino-functionalized SiO2 (SiO 2-NH2) were also prepared via the same method. Fourier transform infrared spectrometer (FTIR) spectroscopy was used to evaluate the structure of SiO2-COOH and nylon 6/SiO2-COOH. The results from thermal gravimetric analysis (TGA) indicated that decomposition temperatures of nylon 6/SiO2-COOH nanocomposites at the 5 wt % of the total weight loss were higher than the pure nylon 6. Differential scanning calorimeter (DSC) studies showed that the melting point (Tm) and degree of crystallinity (Xc) of nylon 6/SiO2-COOH were lower than the pure nylon 6. Mechanical properties results of the nanocomposites showed that nylon 6 with incorporation of SiO2-COOH had better mechanical properties than that of pure nylon 6, nylon 6/SiO2, and nylon 6/SiO2-NH2. The morphology of SiO2, SiO2-NH2, and SiO2-COOH nanoparticles in nylon 6 matrix was observed using SEM measurements. The results revealed that the dispersion of SiO2-COOH nanoparticles in nylon 6 matrix was better than SiO2 and SiO2-NH2 nanoparticles.

AB - Nylon 6/carboxylic acid-functionalized silica nanoparticles (SiO 2-COOH) nanocomposites were prepared by in situ polymerization of caprolactam in the presence of SiO2-COOH. The aim of this work was to study the effect of carboxylic silica on the properties of the nylon 6 through the interfacial interactions between the SiO2-COOH nanoparticles and the nylon 6 matrix. For comparison, pure nylon 6, nylon 6/SiO2 (unmodified) and nylon 6/amino-functionalized SiO2 (SiO 2-NH2) were also prepared via the same method. Fourier transform infrared spectrometer (FTIR) spectroscopy was used to evaluate the structure of SiO2-COOH and nylon 6/SiO2-COOH. The results from thermal gravimetric analysis (TGA) indicated that decomposition temperatures of nylon 6/SiO2-COOH nanocomposites at the 5 wt % of the total weight loss were higher than the pure nylon 6. Differential scanning calorimeter (DSC) studies showed that the melting point (Tm) and degree of crystallinity (Xc) of nylon 6/SiO2-COOH were lower than the pure nylon 6. Mechanical properties results of the nanocomposites showed that nylon 6 with incorporation of SiO2-COOH had better mechanical properties than that of pure nylon 6, nylon 6/SiO2, and nylon 6/SiO2-NH2. The morphology of SiO2, SiO2-NH2, and SiO2-COOH nanoparticles in nylon 6 matrix was observed using SEM measurements. The results revealed that the dispersion of SiO2-COOH nanoparticles in nylon 6 matrix was better than SiO2 and SiO2-NH2 nanoparticles.

KW - in situ polymerization

KW - mechanical properties

KW - nanocomposites

KW - nylon 6

KW - SiO-COOH

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