Preparation and structural characterization of RuII-DMSO and RuIII-DMSO-substituted α-Keggin-type phosphotungstates, [PW11O39RuIIDMSO]5- and [PW 11O39RuIIIDMSO]4-, and catalytic activity for water oxidation

Masahiro Sadakane*, Niklas Rinn, Sachie Moroi, Hiroaki Kitatomi, Tomoji Ozeki, Mariko Kurasawa, Masaya Itakura, Shinjiro Hayakawa, Kazuo Kato, Mayumi Miyamoto, Shuhei Ogo, Yusuke Ide, Tsuneji Sano

*この研究の対応する著者

研究成果: Article査読

28 被引用数 (Scopus)

抄録

RuII-and RuIII-substituted α-Keggin-type phosphotungstates with a dimethyl sulfoxide (DMSO) ligand, [PW 11O39RuIIDMSO]5- (1) and [PW 11O39RuIIIDMSO]4- (2), were synthesized. Compound 1 was prepared by reaction of [PW11O 39]7- with [RuII(DMSO)4]Cl 2 in water at 125 °C under hydrothermal conditions and was isolated as a cesium salt. Compound 2 was prepared by reaction of 1 with bromine in water at 60 °C and was isolated as a cesium salt. The compounds were characterized by cyclic voltammetry, elemental analysis, UV/Vis, IR, 31P NMR, 183W NMR, 1H NMR, and XANES (Ru K-edge and L3-edge)spectroscopic methods. Single crystal structural analysis of 1 revealed that RuII is incorporated in the α-Keggin framework and coordinated by DMSO through a Ru-S bond. Cyclic voltammetry of 1 indicated that the incorporated RuII-DMSO is reversibly oxidizable to the RuIII-DMSO derivative 2. Compound 1 showed catalytic activity for water oxidation in the presence of cerium ammonium nitrate as an oxidant.

本文言語English
ページ(範囲)1467-1474
ページ数8
ジャーナルZeitschrift fur Anorganische und Allgemeine Chemie
637
11
DOI
出版ステータスPublished - 2011 9月
外部発表はい

ASJC Scopus subject areas

  • 無機化学

フィンガープリント

「Preparation and structural characterization of RuII-DMSO and RuIII-DMSO-substituted α-Keggin-type phosphotungstates, [PW11O39RuIIDMSO]5- and [PW 11O39RuIIIDMSO]4-, and catalytic activity for water oxidation」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

引用スタイル