Preparation of acyl(carboxylato)bis(tertiary phosphine)palladium(II) complexes by C-O bond cleavage of carboxylic anhydrides on interaction with palladium(0) complexes. Catalytic hydrogenation of carboxylic anhydrides to aldehydes by palladium complexes

Kazuhiro Nagayama, Futoshi Kawataka, Masato Sakamoto, Isao Shimizu, Akio Yamamoto*

*この研究の対応する著者

研究成果: Article査読

41 被引用数 (Scopus)

抄録

Acyclic anhydrides oxidatively added to [Pd(styrene)(PMeR2)2] (R = Me, 2a; Ph, 2b) under mild conditions with C-O bond cleavage to give the corresponding trans-acyl(carboxylato)palladium complexes 3a-3h. Cyclic acid arthydrides also added to 2a to yield trans-acyl(carboxylato)palladium complexes 4a-4c, while reaction of 2a with phthalic anhydride afforded the palladalactone 4d generated via oxidative addition followed by decarbonylation. The acetyl(acetato)palladium complex 3a reacted with dihydrogen or formic acid to give acetaldehyde and acetic acid. Catalytic hydrogenation of acyclic anhydrides by a palladium complex was achieved to form the corresponding aldehydes and carboxylic acids.

本文言語English
ページ(範囲)573-580
ページ数8
ジャーナルBulletin of the Chemical Society of Japan
72
3
出版ステータスPublished - 1999 3

ASJC Scopus subject areas

  • 化学 (全般)

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「Preparation of acyl(carboxylato)bis(tertiary phosphine)palladium(II) complexes by C-O bond cleavage of carboxylic anhydrides on interaction with palladium(0) complexes. Catalytic hydrogenation of carboxylic anhydrides to aldehydes by palladium complexes」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

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