Preparation of complex copper aluminum double hydroxide phases from copper (II) ammine complex solutions

Yong Park In Yong Park, Kazuyuki Kuroda, Chuzo Kato

    研究成果: Article

    12 引用 (Scopus)

    抄録

    A complex copper aluminum double hydroxide phase with sulfate anions (sulfate phase), Cu0.67Al0.33(OH)2(SO4)0.15(CO3) 0.015·0.5H2O, was prepared by adding a mixed solution of aluminum sulfate and sodium hydroxide to a copper (II) ammine complex solution. Although the X-ray powder diffraction pattern of the sulfate phase was different from those of hydrotalcite-like compounds, the SEM, IR, thermoanalytical data, and anion exchange behavior suggested that the structure was lamellar. The basal spacing depended on the interlayer anion and increased in the following sequence: CO2- 3 s ̌Cl-<Br-<SO2- 4<NO- 3 <CH3OO-. Thermal decomposition processes were also investigated.

    元の言語English
    ページ(範囲)197-203
    ページ数7
    ジャーナルSolid State Ionics
    42
    発行部数3-4
    DOI
    出版物ステータスPublished - 1990

    Fingerprint

    ammines
    Aluminum
    Sulfates
    hydroxides
    Anions
    Copper
    sulfates
    hydrotalcite
    aluminum
    copper
    preparation
    Negative ions
    anions
    Sodium Hydroxide
    Lamellar structures
    X ray powder diffraction
    Diffraction patterns
    sodium hydroxides
    Pyrolysis
    thermal decomposition

    ASJC Scopus subject areas

    • Electrochemistry
    • Physical and Theoretical Chemistry
    • Energy Engineering and Power Technology
    • Materials Chemistry
    • Condensed Matter Physics

    これを引用

    Preparation of complex copper aluminum double hydroxide phases from copper (II) ammine complex solutions. / In Yong Park, Yong Park; Kuroda, Kazuyuki; Kato, Chuzo.

    :: Solid State Ionics, 巻 42, 番号 3-4, 1990, p. 197-203.

    研究成果: Article

    @article{6809c2eb71734053a1150e9f5f1511a3,
    title = "Preparation of complex copper aluminum double hydroxide phases from copper (II) ammine complex solutions",
    abstract = "A complex copper aluminum double hydroxide phase with sulfate anions (sulfate phase), Cu0.67Al0.33(OH)2(SO4)0.15(CO3) 0.015·0.5H2O, was prepared by adding a mixed solution of aluminum sulfate and sodium hydroxide to a copper (II) ammine complex solution. Although the X-ray powder diffraction pattern of the sulfate phase was different from those of hydrotalcite-like compounds, the SEM, IR, thermoanalytical data, and anion exchange behavior suggested that the structure was lamellar. The basal spacing depended on the interlayer anion and increased in the following sequence: CO2- 3 s ̌Cl-<Br-<SO2- 4<NO- 3 <CH3OO-. Thermal decomposition processes were also investigated.",
    author = "{In Yong Park}, {Yong Park} and Kazuyuki Kuroda and Chuzo Kato",
    year = "1990",
    doi = "10.1016/0167-2738(90)90008-F",
    language = "English",
    volume = "42",
    pages = "197--203",
    journal = "Solid State Ionics",
    issn = "0167-2738",
    publisher = "Elsevier",
    number = "3-4",

    }

    TY - JOUR

    T1 - Preparation of complex copper aluminum double hydroxide phases from copper (II) ammine complex solutions

    AU - In Yong Park, Yong Park

    AU - Kuroda, Kazuyuki

    AU - Kato, Chuzo

    PY - 1990

    Y1 - 1990

    N2 - A complex copper aluminum double hydroxide phase with sulfate anions (sulfate phase), Cu0.67Al0.33(OH)2(SO4)0.15(CO3) 0.015·0.5H2O, was prepared by adding a mixed solution of aluminum sulfate and sodium hydroxide to a copper (II) ammine complex solution. Although the X-ray powder diffraction pattern of the sulfate phase was different from those of hydrotalcite-like compounds, the SEM, IR, thermoanalytical data, and anion exchange behavior suggested that the structure was lamellar. The basal spacing depended on the interlayer anion and increased in the following sequence: CO2- 3 s ̌Cl-<Br-<SO2- 4<NO- 3 <CH3OO-. Thermal decomposition processes were also investigated.

    AB - A complex copper aluminum double hydroxide phase with sulfate anions (sulfate phase), Cu0.67Al0.33(OH)2(SO4)0.15(CO3) 0.015·0.5H2O, was prepared by adding a mixed solution of aluminum sulfate and sodium hydroxide to a copper (II) ammine complex solution. Although the X-ray powder diffraction pattern of the sulfate phase was different from those of hydrotalcite-like compounds, the SEM, IR, thermoanalytical data, and anion exchange behavior suggested that the structure was lamellar. The basal spacing depended on the interlayer anion and increased in the following sequence: CO2- 3 s ̌Cl-<Br-<SO2- 4<NO- 3 <CH3OO-. Thermal decomposition processes were also investigated.

    UR - http://www.scopus.com/inward/record.url?scp=0025506890&partnerID=8YFLogxK

    UR - http://www.scopus.com/inward/citedby.url?scp=0025506890&partnerID=8YFLogxK

    U2 - 10.1016/0167-2738(90)90008-F

    DO - 10.1016/0167-2738(90)90008-F

    M3 - Article

    VL - 42

    SP - 197

    EP - 203

    JO - Solid State Ionics

    JF - Solid State Ionics

    SN - 0167-2738

    IS - 3-4

    ER -