Preparation of electroactive poly (p-phenylene) film by means of electrochemical oxidation and reduction methods

Shinichi Komaba, Toshiyuki Momma, Ami Usui, Tetsuya Osaka

研究成果: Article

抄録

We tried to prove the merit of electrochemical reductive polymerization (ERP) original character of which is to control polymerization site on the preparation of π-conjugated polymer film. As the results, an electroactive poly(p-phenylene) film formed by ERP demonstrated a reversible higher redox property and narrower energy band gap in comparison with the film formed by electrochemical oxidative polymerization of biphenyl. So it is efficient to use EPR as the film formation of π-conjugated polymer film.

元の言語English
ページ(範囲)204-207
ページ数4
ジャーナルElectrochemistry
65
発行部数3
出版物ステータスPublished - 1997
外部発表Yes

Fingerprint

Electrochemical oxidation
Electropolymerization
Conjugated polymers
Polymer films
Polymerization
Band structure
Paramagnetic resonance
Energy gap
poly-para-phenylene

ASJC Scopus subject areas

  • Electrochemistry

これを引用

@article{1b5f456fedc74925872813287f4a0d98,
title = "Preparation of electroactive poly (p-phenylene) film by means of electrochemical oxidation and reduction methods",
abstract = "We tried to prove the merit of electrochemical reductive polymerization (ERP) original character of which is to control polymerization site on the preparation of π-conjugated polymer film. As the results, an electroactive poly(p-phenylene) film formed by ERP demonstrated a reversible higher redox property and narrower energy band gap in comparison with the film formed by electrochemical oxidative polymerization of biphenyl. So it is efficient to use EPR as the film formation of π-conjugated polymer film.",
keywords = "Electropolymerization, Poly(p-phonylono)",
author = "Shinichi Komaba and Toshiyuki Momma and Ami Usui and Tetsuya Osaka",
year = "1997",
language = "English",
volume = "65",
pages = "204--207",
journal = "Electrochemistry",
issn = "1344-3542",
publisher = "Electrochemical Society of Japan",
number = "3",

}

TY - JOUR

T1 - Preparation of electroactive poly (p-phenylene) film by means of electrochemical oxidation and reduction methods

AU - Komaba, Shinichi

AU - Momma, Toshiyuki

AU - Usui, Ami

AU - Osaka, Tetsuya

PY - 1997

Y1 - 1997

N2 - We tried to prove the merit of electrochemical reductive polymerization (ERP) original character of which is to control polymerization site on the preparation of π-conjugated polymer film. As the results, an electroactive poly(p-phenylene) film formed by ERP demonstrated a reversible higher redox property and narrower energy band gap in comparison with the film formed by electrochemical oxidative polymerization of biphenyl. So it is efficient to use EPR as the film formation of π-conjugated polymer film.

AB - We tried to prove the merit of electrochemical reductive polymerization (ERP) original character of which is to control polymerization site on the preparation of π-conjugated polymer film. As the results, an electroactive poly(p-phenylene) film formed by ERP demonstrated a reversible higher redox property and narrower energy band gap in comparison with the film formed by electrochemical oxidative polymerization of biphenyl. So it is efficient to use EPR as the film formation of π-conjugated polymer film.

KW - Electropolymerization

KW - Poly(p-phonylono)

UR - http://www.scopus.com/inward/record.url?scp=6044241154&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=6044241154&partnerID=8YFLogxK

M3 - Article

VL - 65

SP - 204

EP - 207

JO - Electrochemistry

JF - Electrochemistry

SN - 1344-3542

IS - 3

ER -