Processing of conductive polymers generally employ organic solvents such as acetonitrile. This work report electrochemical synthesis of a conductive polymer thin film in surpercritical carbon dioxide (scCO2). Iron 5-(3-thienyl)-10,15,20-triethylporphyrin film synthesized in scCO2 was analyzed by scanning electron microscopy and laser microscopy. It was revealed that the thickness and smoothness of the porphyrin film synthesized in scCO2 was 1/10 of those of the film synthesized in dichloromethane.
|出版ステータス||Published - 2006 10月 18|
|イベント||55th SPSJ Annual Meeting - Nagoya, Japan|
継続期間: 2006 5月 24 → 2006 5月 26
|Conference||55th SPSJ Annual Meeting|
|Period||06/5/24 → 06/5/26|
ASJC Scopus subject areas