Preparation of imides via the palladium-catalyzed coupling reaction of organoborons with methyl N -[methoxy(methylthio)methylene]carbamate as a one-carbon elongation reaction

Takuhei Tomizawa, Kohei Orimoto, Takashi Niwa, Masahisa Nakada*

*この研究の対応する著者

研究成果: Article査読

17 被引用数 (Scopus)

抄録

The preparation of imides via the palladium-catalyzed coupling reaction as a one-carbon elongation reaction is described. The palladium-catalyzed coupling reaction of aryl-, alkyl-, and alkenylborons with N-[methoxy(methylthio) methylene]carbamate in the presence of Cu(I) thiophene-2-carboxylate (CuTC) affords imino ethers that are converted to the corresponding imides by acidic hydrolysis in high yield. The imino ethers are also useful for preparing the corresponding ester without using carbon monoxide.

本文言語English
ページ(範囲)6294-6297
ページ数4
ジャーナルOrganic Letters
14
24
DOI
出版ステータスPublished - 2012 12月 21

ASJC Scopus subject areas

  • 生化学
  • 物理化学および理論化学
  • 有機化学

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