Preparation of intercalation compounds between V2O5 gel and bipyridyl metal complexes

Teruyuki Nakato*, Tsuyoshi Ise, Yoshiyuki Sugahara, Kazuyuki Kuroda, Chuzo Kato

*この研究の対応する著者

研究成果: Article査読

18 被引用数 (Scopus)

抄録

The intercalation of tris-bipyridyl metal complexes (M(bpy)32+, M=Ru, Ni, and Co) into the interlayer region of vanadium pentoxide gel (V2O5·nH2O) was confirmed for the first time. The intercalation of the guest species was conducted by the reaction of the complexes with undried V2O5 gel. The saturated amount of adsorbed M(bpy)32+ was less than the ion exchange capacity of the V2O5 gel because of bulkiness of M(bpy)32+. The transition temperature to orthorhombic V2O5 was higher than that of original V2O5 gel, indicating the stabilization of the layered structure by the intercalation.

本文言語English
ページ(範囲)309-315
ページ数7
ジャーナルMaterials Research Bulletin
26
4
DOI
出版ステータスPublished - 1991 4

ASJC Scopus subject areas

  • 材料科学(全般)
  • 凝縮系物理学
  • 材料力学
  • 機械工学

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