Preparation of Mesoporous Basic Oxides through Assembly of Monodispersed Mg–Al Layered Double Hydroxide Nanoparticles

Yuya Oka, Yoshiyuki Kuroda, Takamichi Matsuno, Keigo Kamata, Hiroaki Wada, Atsushi Shimojima, Kazuyuki Kuroda

    研究成果: Article

    16 引用 (Scopus)

    抜粋

    Mesoporous basic Mg–Al mixed metal oxides (MMOs) with a high surface area and large pore size have been prepared through the assembly of monodispersed layered double hydroxide nanoparticles (LDHNPs) with block copolymer templates. The particle sizes of the LDHNPs were mainly controlled by varying the concentration of tris(hydroxymethyl)aminomethane (THAM), which was used as a surface stabilizing agent. LDHNPs and micelles of a block copolymer (Pluronic F127) were assembled to form a composite. The composites were calcined to transform them into mesoporous MMOs and to remove the templates. The Brunauer–Emmett–Teller surface areas, mesopore sizes, and pore volumes increased as a result of using the templates. Moreover, the pore sizes of the mesoporous MMOs could be controlled by using LDHNPs of different sizes. The mesoporous MMOs prepared from the LDHNPs showed much higher catalytic activity than a conventional MMO catalyst for the Knövenagel condensation of ethyl cyanoacetate with benzaldehyde. The mesoporous MMO catalyst prepared using the smallest LDHNPs, about 12 nm in size, showed the highest activity. Therefore, the use of monodispersed LDHNPs and templates is effective for preparing highly active mesoporous solid base catalysts.

    元の言語English
    ページ(範囲)9362-9368
    ページ数7
    ジャーナルChemistry - A European Journal
    23
    発行部数39
    DOI
    出版物ステータスPublished - 2017 7 12

      フィンガープリント

    ASJC Scopus subject areas

    • Chemistry(all)

    これを引用