Preparation of poly(1,4‐phenylene)s by electro‐oxidative polymerization

Kenichi Oyaizu, Kimihisa Yamamoto, Toshio Asada, Hiroyuki Nishide, Eishun Tsuchida

研究成果: Article

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The effect of substituents on the electropolymerization of benzene derivatives and the redox properrties of the corresponding polymers were determined using Brown's substituent constants (σ+). Electron‐donating groups lower the oxidation potential by which increase in the current efficiency was observed. However, stabilization of the produced cation radicals by the electron‐donating groups resulted in a decrease in the polymerization efficiency. The appropriate values of σ+ for the efficient polymerization ranged near −1.5.

元の言語English
ページ(範囲)254-257
ページ数4
ジャーナルPolymers for Advanced Technologies
6
発行部数4
DOI
出版物ステータスPublished - 1995

ASJC Scopus subject areas

  • Polymers and Plastics

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