PREPARATION OF POLY(P-PHENYLENE) BY ELECTROOXIDATIVE POLYMERIZATION IN ACIDIC MEDIA.

Kimihisa Yamamoto*, Toshio Asada, Hiroyuki Nishide, Eishun Tsuchida

*この研究の対応する著者

研究成果: Article査読

33 被引用数 (Scopus)

抄録

The electro-oxidative polymerization of benzene in the presence of strong acids yields poly(p-phenylene) efficiently. A strong protonic acid such as trifluoromethanesulfonic acid or Lewis acid such as an aluminum trichloride forms a complex with benzene and reduces the oxidation potential of benzene to 1. 7 V, which brings about the high current efficiency. The acids act both as an electrolyte and as a catalyst in this polymerization of benzene.

本文言語English
ページ(範囲)1731-1734
ページ数4
ジャーナルBulletin of the Chemical Society of Japan
61
5
出版ステータスPublished - 1988 5月

ASJC Scopus subject areas

  • 化学 (全般)

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