Preparation of soluble AIN precursors in a LiAlH4-CH3NH2·HCl-(CH3) 2NH-HCl system

Seiichi Koyama; Yasuo Saito; Yoshiyuki Sugahara; Kazuyuki Kuroda

doi:10.1246/cl.1997.1227

Preparation of soluble AIN precursors in a LiAlH₄-CH₃NH₂·HCl-(CH₃) ₂NH-HCl system

Seiichi Koyama, Yasuo Saito, Yoshiyuki Sugahara^*, Kazuyuki Kuroda

^*この研究の対応する著者

先進理工学部

研究成果: Article › 査読

2 被引用数 (Scopus)

抄録

Novel AlN precursors have been prepared by reactions in a LiAlH₄-CH₃NH₂·HCl-(CH₃) ₂NH·HCl system with several nominal CH₃NH₂·HCl:(CH₃) ₂NH·HCl (M:D) ratios (M:D=4:1, 6:1 and 8:1). Considerable amounts of precursors were soluble in both tetrahydrofuran and benzene. Soluble precursors consist of polymeric/oligomeric species possessing both [H₂AlNMe₂] and [HAlNMe] units, and ring-type (H₂AlNMe₂)₃ was also present only if M:D=4:1. The precursors were converted into single-phase AIN with relatively high ceramic yields (up to 58 %) by pyrolysis at 1600°C under Ar.

本文言語	English
ページ（範囲）	1227-1228
ページ数	2
ジャーナル	Chemistry Letters
号	12
DOI	https://doi.org/10.1246/cl.1997.1227
出版ステータス	Published - 1997 1 1

ASJC Scopus subject areas

化学 (全般)

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10.1246/cl.1997.1227

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引用スタイル

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abstract = "Novel AlN precursors have been prepared by reactions in a LiAlH4-CH3NH2·HCl-(CH3) 2NH·HCl system with several nominal CH3NH2·HCl:(CH3) 2NH·HCl (M:D) ratios (M:D=4:1, 6:1 and 8:1). Considerable amounts of precursors were soluble in both tetrahydrofuran and benzene. Soluble precursors consist of polymeric/oligomeric species possessing both [H2AlNMe2] and [HAlNMe] units, and ring-type (H2AlNMe2)3 was also present only if M:D=4:1. The precursors were converted into single-phase AIN with relatively high ceramic yields (up to 58 %) by pyrolysis at 1600°C under Ar.",

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AU - Kuroda, Kazuyuki

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AB - Novel AlN precursors have been prepared by reactions in a LiAlH4-CH3NH2·HCl-(CH3) 2NH·HCl system with several nominal CH3NH2·HCl:(CH3) 2NH·HCl (M:D) ratios (M:D=4:1, 6:1 and 8:1). Considerable amounts of precursors were soluble in both tetrahydrofuran and benzene. Soluble precursors consist of polymeric/oligomeric species possessing both [H2AlNMe2] and [HAlNMe] units, and ring-type (H2AlNMe2)3 was also present only if M:D=4:1. The precursors were converted into single-phase AIN with relatively high ceramic yields (up to 58 %) by pyrolysis at 1600°C under Ar.

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