Proton-coupled electron transfer from sulfur: A S-H/S-D kinetic isotope effect of ≥ 31.1

Takumi Konno, Yu Chikamoto, Ken Ichi Okamoto, Tadashi Yamaguchi, Tasuku Ito, Masakazu Hirotsu

研究成果: Article査読

38 被引用数 (Scopus)

抄録

Not bound to a metal and yet still involved in proton-coupled electron transfer - this is the distinguishing property of the sulfur center of the complex [Os(IV)(tpy)(Cl)2{NS(H)C6H3Me2}]+ (1, tpy = terpyridine). In fact 1 also provides the first example of proton-coupled electron transfer involving a sulfur atom. This reaction is notable for the large magnitude of the kinetic isotope effect.

本文言語English
ページ(範囲)4101-4104
ページ数4
ジャーナルAngewandte Chemie - International Edition
39
22
DOI
出版ステータスPublished - 2000 11月 17
外部発表はい

ASJC Scopus subject areas

  • 触媒
  • 化学 (全般)

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