QUANTUM MECHANICAL ASPECTS OF O//2 ACTIVATION BY TRANSITION METAL MACROCYLES: RING-ASSISTED FOUR-ELECTRON REDUCTION.

C. Fierro, A. Tanaka, Daniel Alberto Scherson, E. B. Yeager

研究成果: Conference article査読

抄録

Iron and cobalt macrocycles have been extensively studied over the past two decades as catalysts for the electrochemical reduction of dioxygen. The importance of such investigations is two-fold. First, the high activity exhibited by some of these compounds has opened the possibility of replacing platinum in fuel cell applications and second, a systematic examination of the electrocatalytic reduction of O//2 by transition metal macrocycles in general may provide further insight into the factors involved in the overall phenomenon of O//2 activation. This work will focus attention on the modification in the mechanism of O//2 reduction induced by changes in the oxidation state of a specific macrocycle. An iron porphyrasine was selected for this study.

本文言語English
ページ(範囲)909-910
ページ数2
ジャーナルElectrochemical Society Extended Abstracts
85-1
出版ステータスPublished - 1985 1 1
外部発表はい

ASJC Scopus subject areas

  • Engineering(all)

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