RADICAL COPOLYMERIZATION OF PROTO-HEMIN DIMETHYL ESTER.

Hiroyuki Nishide, Kenichi Shinohara, Eishun Tsuchida

研究成果: Article査読

15 被引用数 (Scopus)

抄録

Data are presented which demonstrate that iron(III) proto-porphyrin IX dimethyl ester (HDME) can copolymerize with pi -conjugated monomers binding at one end of the polymer chain. Apparent Q, e values of HDME were Q equals 70 and e equals minus 0. 17. The copolymerization of HDME with pi -unconjugated monomer was feasible by using pi -conjugated monomer as a third component. When unconjugated vinylimidazoles were used as monomers, the obtained ternary copolymers of HDME formed intramacromolecular complexes of iron(II) porphyrin with vinylimidazole residues, which gave stable carbon monoxide adducts.

本文言語English
ページ(範囲)1109-1117
ページ数9
ジャーナルJournal of polymer science. Part A-1, Polymer chemistry
19
5
出版ステータスPublished - 1981 5
外部発表はい

ASJC Scopus subject areas

  • Engineering(all)

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