抄録
Octahedral fac(S)-[Con(III)(aet)3] molecules (aet = NH2CH2CH2S-) react with square-planar Pd(II) ions to form a sulfur-bridged Co2/(III)Pd(II) trinuclear complex [Pd{Co(aet)3}2]2+, accompanied by the geometrical isomerization from fac(S) to met(S). This complex was found to act as a sulfur-donating trinuclear-metalloligand toward linear Au(I) and Ag(I) ions to afford Co4/(III)Pd2/(II)M2/(I) metallacycles with 16 chiral centers, [M2/(I){Pd(II)[Co(III)(aet)3]2}2]6+ (M = Ag, Au (1)), which were successfully resolved into the (Δ)4(R)12 and (Λ)4(S)12 enantiomers.
本文言語 | English |
---|---|
ページ(範囲) | 4098-4101 |
ページ数 | 4 |
ジャーナル | Angewandte Chemie - International Edition |
巻 | 39 |
号 | 22 |
DOI | |
出版ステータス | Published - 2000 11月 17 |
外部発表 | はい |
ASJC Scopus subject areas
- 触媒
- 化学 (全般)