Reaction of a stable digermyne with acetylenes: Synthesis of a 1,2-digermabenzene and a 1,4-digermabarrelene#

Tomohiro Sugahara, Jing Dong Guo, Takahiro Sasamori, Yusaku Karatsu, Yukio Furukawa, Arturo Espinosa Ferao, Shigeru Nagase, Norihiro Tokitoh

研究成果: Article査読

39 被引用数 (Scopus)

抄録

Reactions between acetylenes and a stable digermyne bearing 4-t-Bu-2,6-[CH(SiMe3)2]2-C6H2 (Tbb) groups afforded the corresponding stable 1,2-digermabenzenes together with the respective 1,4-digermabarrelenes. The properties of the obtained products and the reaction mechanism are discussed on the basis of experimental and theoretical results. Especially, the aromaticity of the newly obtained 1,2-digermabenzene has been discussed on the detailed calculations, revealing its aromatic character to some degree.

本文言語English
ページ(範囲)1375-1384
ページ数10
ジャーナルBulletin of the Chemical Society of Japan
89
11
DOI
出版ステータスPublished - 2016

ASJC Scopus subject areas

  • 化学 (全般)

引用スタイル