Reactions of 1,2-propadienyl sulfides with aldehydes and acetals catalyzed by BF<inf>3</inf> · OEt<inf>2</inf>

Koichi Narasaka, Takanori Shibata, Yujiro Hayashi

研究成果: Article

4 引用 (Scopus)

抄録

Ene reaction proceeds between 1-alkyl-1,2-propadienyl sulfides and aldehydes in the presence of BF<inf>3</inf> · OEt<inf>2</inf> to afford 1,3-dienes possessing an alkylthio group. On the other hand, the reactions of 1-silyl-1,2-propadienyl sulfides with aldehydes or their dimethylacetals give aldol-type addition products, a-methylene acylsilanes.

元の言語English
ページ(範囲)2825-2830
ページ数6
ジャーナルBulletin of the Chemical Society of Japan
65
発行部数10
出版物ステータスPublished - 1992 10 1
外部発表Yes

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Acetals
Sulfides
Aldehydes
3-hydroxybutanal

ASJC Scopus subject areas

  • Chemistry(all)

これを引用

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abstract = "Ene reaction proceeds between 1-alkyl-1,2-propadienyl sulfides and aldehydes in the presence of BF3 · OEt2 to afford 1,3-dienes possessing an alkylthio group. On the other hand, the reactions of 1-silyl-1,2-propadienyl sulfides with aldehydes or their dimethylacetals give aldol-type addition products, a-methylene acylsilanes.",
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T1 - Reactions of 1,2-propadienyl sulfides with aldehydes and acetals catalyzed by BF3 · OEt2

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AU - Shibata, Takanori

AU - Hayashi, Yujiro

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N2 - Ene reaction proceeds between 1-alkyl-1,2-propadienyl sulfides and aldehydes in the presence of BF3 · OEt2 to afford 1,3-dienes possessing an alkylthio group. On the other hand, the reactions of 1-silyl-1,2-propadienyl sulfides with aldehydes or their dimethylacetals give aldol-type addition products, a-methylene acylsilanes.

AB - Ene reaction proceeds between 1-alkyl-1,2-propadienyl sulfides and aldehydes in the presence of BF3 · OEt2 to afford 1,3-dienes possessing an alkylthio group. On the other hand, the reactions of 1-silyl-1,2-propadienyl sulfides with aldehydes or their dimethylacetals give aldol-type addition products, a-methylene acylsilanes.

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